Microstructures
by George Langford, Sc.D., Massachusetts Institute of Technology, Cambridge, MA, 1966
Copyright©
2005 by George Langford
Non Ferrous Alloys - Lesson 4 - First specimen
Aluminum -- silicon alloy at 50X etched
This is an aluminum - 5% silicon alloy casting. 

Note the unusual distribution of phases in the eutectic microconstituent.

The photomicrograph at left was taken at 50X magnification.  Below, the magnification is 500X.

The etchant used here was a one percent solution of hydrogen fluoride (HF) in water.  Don't try making or using this etchant without first preparing yourself for the extreme hazard to your person from the HF acid.
Aluminum - silicon alloy at 500X etched
The microstructure consists of alpha plus coarse eutectic.  The eutectic in turn is composed of a mixture of additional alpha plus metallic silicon.

There is "too much" primary alpha for the given composition, so there has been eutectic divorcement, wherein the later alpha that formed was deposited on the primary alpha.  Eventually, the eutectic formed in the classical coupled manner.

This alloy has, in addition to the 4.5% to 6.0% silicon, 0.6% copper and 1.0% iron.  Silicon platelets are all that is left of the eutectic.  Some precipitation has occured in the alpha.
Aluminum - silicon phase diagram
The equilibrium aluminum - silicon phase diagram is shown at left to help you follow the explanation of the sequence of eutectic formation given above. 

Note that this alloy is intended to have both primary alpha and eutectic alpha plus silicon in the two-phase microstructure.




Specimen 2 is a higher silicon aluminum alloy.