Microstructures
by George Langford, Sc.D., Massachusetts Institute of Technology, Cambridge, MA, 1966
Copyright©
2005 by George Langford
Cast Irons, High Alloy Steels, and Superalloys - Lesson 1 - Fifth specimen
Bullseye nodular iron at 500X etched This nodular cast iron has a bullseye microstructure due to an intermediate cooling rate.  The magnification is 500X.

Can you tell whether the white rings are ferrite or cementite ?

Is there a fundamental reason why you wouldn't expect the rings to be cementite ?



Think about this while looking at the metastable/stable iron - carbon phase diagrams and then look at the answers below.



























Explanation:  The white rings have to be ferrite because iron carbide cannot be stable in direct contact with graphite.  Also, the white rings are continuous with the majority (ferrite) phase in the pearlite.  The cementite lamellae in this pearlite are quite coarsely spaced, indicating slow cooling during the formation of the pearlite. 
This microstructure combines wear resistance (due to the relatively high hardness of the pearlite) with toughness because the ferrite rings relieve the strain concentrations around the graphite nodules during deformation.
Specimen 6 is a white cast iron.