Microstructures
by George Langford, Sc.D., Massachusetts Institute of Technology, Cambridge, MA, 1966
Copyright©
2005 by George Langford
Surface Coatings and Heat Resisting Alloys - Lesson 3 - Eighth specimen
This series of images shows an unsuccessful attempt to coat a low carbon steel with a heat resistant alloy by welding.
All three photomicrographs are at 100X original magnification.
Weld overlay at 100X etched (greyscale)
This photomicrograph shows that there is no zone of intermixing between the low carbon steel at left and the  heat resistant alloy at right.

I gave up trying to correct the color balance of this image, so it is presented in greyscale to preserve a degree of contrast between the two microstructures.
Steel substrate of the overlay at 100X etched
This is the steel substrate, in color this time.
Overlay metal at 100X etched
The cast microstructure of the heat resistant alloy, shown in color at left, has two phases.  It is called Stellite and is based on cobalt plus 30% copper, 10% tungsten, 1% carbon, and 1% iron.

The coating, even though its microstructure is sound, would probably spall off the steel in service due to the lack of any metallurgical bonding between the coating and the substrate.
Specimen 9 shows a better coating process.