Microstructures
by George Langford, Sc.D., Massachusetts Institute of Technology, Cambridge, MA, 1966
Copyright©
2005 by George Langford
Low Alloy Steels - Lesson 4 - Ninth specimen
Nitrided thread gauge at 200X etched
This is a nitrided thread gauge whose threads spalled off because of decarburization. 

The image at left was made at 200X with a Nital etch.
Nitrided thread gauge at 500X etched
The second image is at 500X.






What is your remedy ?




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Answer:  The user had attempted to save money by using rough stock whose diameter was barely adequate to make the gauge.  It had been decarburized to a normal degree during hot rolling at the mill.  The gauge was to be hardened after rough machining, and then was to be ground to size after tempering but before nitriding, which is OK.  However, nitrides formed at the ferrite grain boundaries, where diffusion is faster; furthermore, diffusion is faster in the non close packed BCC ferrite than it is in close packed FCC austenite.  Therefore, a disuptive volume increase occurred, spalling the threads.  Some Widmanstaetten precipitation of the nitrides is evident as well.
Specimen 10 was nitrided in excessively dissociated ammonia.