Microstructures
by George Langford, Sc.D., Massachusetts Institute of Technology, Cambridge, MA, 1966
Copyright©
2005 by George Langford
Non Ferrous Alloys - Lesson 2 - Fourth specimen
Muntz metal water pipe at 500X etched
This is a Muntz metal water pipe which failed after 25 years in service.  What type of failure is it ?  Look at both frames before deciding.  Each one is at 500X.

The upper photomicrograph was taken near the edge ...
Muntz metal water pipe 500X etched
The lower one was taken in the interior of the pipe wall.






Now look at the explanation.









This is dezincification, which occurs by selective leaching of zinc (from the lemon yellow beta phase) by corrosive water.  Copper remains behind as a spongy mass because it is reprecupitated as metallic copper after the disappearance of the zinc.  The pipe failed first at the threaded joints because of the reduction in wall thickness by the cutting of the threads.  Manufacturers persist in using this alloy in cheap lathe-turned parts (faucet-washer screws and toilet valve components especially) because of its superior machinability.
The fifth specimen is an example of chemically induced cracking.