Microstructures
by George Langford, Sc.D., Massachusetts Institute of Technology, Cambridge, MA, 1966
Copyright©
2005 by George Langford
Non Ferrous Alloys - Lesson 1 - Second specimen
As cast tough pitch copper at 200X etched The second specimen, shown in the three frames on this page, is as-cast tough pitch copper.  The photomicrograph at left, taken at 200X, shows copper dendrites in a matrix of copper/copper oxide eutectic.  Note the differently oriented copper grains, each one containing a distinct dendritic pattern.
Copper-copper oxide phase diagram
This copper-copper oxide phase diagram says that liquid copper can dissolve a great deal of oxygen (as copper oxide) but that the solubility of the oxide in solid copper is much less.
Tough pitch copper at 500X etched
The second photomicrograph of this specimen, taken at 500X, illustrates a divorced eutectic.  Copper continued to precipitate on existing copper dendrites during the solidification of this specimen.  There is no distinct eutectic microconstituent, only small islands of oxide.




Specimen 3 demonstrates the deoxidation of copper.