Microstructures
by George Langford, Sc.D., Massachusetts Institute of Technology, Cambridge, MA, 1966
Copyright©
2005 by George Langford
Non Ferrous Alloys - Lesson 1 - Fifth specimen
Cast alopha brass 50X etched
This is a cast alpha brass at 50X.  It has about 30% zinc.  Note the [very few] grain boundaries; these are much easier to see than those in the preceding specimen.  There is brightness contrast because of the differring reflectivity of the variously oriented dendrites.  Each grain is a single, separate dendrite with many closely spaced secondary arms.  Note the difference between the relatively long primary and short secondary dendrite arms.  There is coring in this specimen, too.
Copper - Zinc phase diagram
The copper - zinc equilibrium diagram says that the beta  phase is not stable at room temperature, even though it is the normal microconstituent in higher zinc alloys.  Beta phase is not present in this specimen because zinc diffuses quite rapidly in copper (compared to tin in copper, for example).  Any beta phase in the zinc-enriched last metal to freeze has dissolved into the alpha phase.
Dendrite arm spacing is a function of cooling rate
The dendrite arm spacing of a casting is indicative of the cooling rate during freezing - coarse dendrites forming in large castings and fine dendrites in small castings.









Specimen 6 is Muntz metal, an alloy with 40% zinc.