Microstructures
by George Langford, Sc.D., Massachusetts Institute of Technology, Cambridge, MA, 1966
Copyright©
2005 by George Langford
Non Ferrous Alloys - Lesson 2 - Sixth specimen
Muntz metal heat exchanger at 100X etched
Here are two cross sections of a Muntz metal heat exchanger tube which failed in service.  Water was circulated through the tubing to cool air, compressed to 100 pounds per square inch, that was flowing past the  outside of the tube.  The pipe collapsed because the corrosion weakened it and because the air pressure outside the tube was greater than the water pressure inside the tube.

The photomicrograph at left was made at the point of failure at 100X ...
Muntz metal heat exchanger at  100X etched
... and the second photomicrograph was taken at a remote location where the pipe was still round, also at 100X.






Think about this example before seeing the explanation.










Explanation
The coarse microstructure at the point of failure is indicative of overheating, while the dezincification at the remote part of the heat exchanger occurred on the outside of the pipe.  The external dezincification removes blame from the water ... and the coarsening of the microstructure at the point of failure strongly hints that the air was not simply corrosive, but too hot as well.





The seventh specimen is a failure combining corrosion with fatigue.